水质 挥发性石油烃(C6-C9)的测定吹扫捕集Tenax管
水质 挥发性石油烃(C6-C9)的测定吹扫捕集Tenax管 详细信息:
名称:吸附管
规格:1/4*3.5
填料:200mg
形状:U,直管
型号:TENAX-TA
1 适用范围
本标准规定了测定水中挥发性石油烃(C6-C9)的吹扫捕集/气相色谱法。
本标准适用于地表水、地下水、海水、生活污水和工业废水中挥发性石油烃(C6-C9) 的测定。
当取样量为10.0ml时,本标准测定的挥发性石油烃(C6-C9)方法检出限为0.02mg/L, 测定下限为0.08 mg/L。
当取样量为20.0ml时,本标准测定的挥发性石油烃(C6-C9)方法检出限为0.01mg/L, 测定下限为0.04 mg/L。
2 规范性引用文件
本标准引用了下列文件或其中的条款。凡是不注日期的引用文件,其有效版本适用于本标准。
GB 17378.3 海洋监测规范 第3部:样品采集、贮存与运输
HJ/T 91 地表水和污水监测技术规范
HJ/T 164 地下水环境监测技术规范
3 术语和定义
挥发性石油烃(C6-C9) volatile petroleum hydrocarbons
在本标准规定的条件下,在气相色谱图上保留时间介于2-甲基戊烷(包含)与n-C10H22 (不包含)之间的物质。
注:该定义下的挥发性石油烃(C6-C9)包括脂肪烃,脂环烃,芳香烃或烷基化的芳香烃等。
4 方法原理
样品中的目标化合物经高纯氮气吹扫后吸附于捕集管中,将捕集管加热并以高纯氮气反吹,被热脱附出来的组分经气相色谱柱分离后,用氢火焰离子化检测器(FID)检测,根据保留时间窗定性,外标法定量。
水质 挥发性石油烃(C6-C9)的测定吹扫捕集Tenax管 测试谱图:











Water quality Determination of volatile petroleum hydrocarbons (C6-C9) Purge and trap Tenax tube
Water quality Determination of volatile petroleum hydrocarbons (C6-C9) Purge and trap Tenax pipes Details:
Name: Adsorption tube
Specification: 1/4*3.5
Filler: 200mg
Shape: U, straight pipe
Model: TENAX-TA
1 Scope of application
This standard specifies the purge and trap/gas chromatography method for the determination of volatile petroleum hydrocarbons (C6-C9) in water.
This standard applies to the determination of volatile petroleum hydrocarbons (C6-C9) in surface water, groundwater, seawater, domestic sewage and industrial wastewater.
When the sampling volume is 10.0ml, the detection limit of the volatile petroleum hydrocarbon (C6-C9) method determined by this standard is 0.02mg/L, and the lower limit of determination is 0.08 mg/L.
When the sampling volume is 20.0ml, the detection limit of the volatile petroleum hydrocarbon (C6-C9) method determined by this standard is 0.01mg/L, and the lower limit of determination is 0.04 mg/L.
2 Normative references
This standard refers to the following documents or their clauses. For undated reference documents, the effective version is applicable to this standard.
GB 17378.3 Marine Monitoring Specification Part 3: Sample Collection, Storage and Transportation
HJ/T 91 Technical specification for surface water and sewage monitoring
HJ/T 164 Technical Specification for Groundwater Environmental Monitoring
3 Terms and definitions
Volatile petroleum hydrocarbons (C6-C9) volatile petroleum hydrocarbons
Under the conditions specified in this standard, the retention time on the gas chromatogram is between 2-methylpentane (included) and n-C10H22 (not included).
Note: Volatile petroleum hydrocarbons (C6-C9) under this definition include aliphatic hydrocarbons, alicyclic hydrocarbons, aromatic hydrocarbons or alkylated aromatic hydrocarbons.
4 Principles of the method
The target compound in the sample is purged by high-purity nitrogen and adsorbed in the trapping tube. The trapping tube is heated and backflushed with high-purity nitrogen. After the thermally desorbed components are separated by a gas chromatography column, they are separated by a hydrogen flame Ionization detector (FID) detection, qualitative according to the retention time window, quantitative with external standard method.
Water quality Determination of volatile petroleum hydrocarbons (C6-C9) Purge and trap Tenax tube Test spectrum:
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