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产品介绍

Lithium aluminium deuteride, 98 atom% D, for NMR

MSDS    Specifications    Applications    Categories    3D model    Molfile

General	^
Product Name	Lithium aluminium deuteride
CAS RN	14128-54-2
ACD Code	MFCD00044245
Structure
Molecular Formula	Al D4 Li
Molecular weight	41.98
Pack size	Catalog Qty / UM Price (CNY)    185670050  5 GR  1499.7 Order Check stock
Physical	^
Melting Point (°C)	175
Safety	^
GHS Pictogram
GHS Signal Word	Danger
GHS H statment	H260: In contact with water releases flammable gases which may ignite spontaneously   H314: Causes severe skin burns and eye damage
GHS P statment	P223: Keep away from any possible contact with water, because of violent reaction and possible flash fire   P280: Wear protective gloves/protective clothing/eye protection/face protection   P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing   P260: Do not breathe dust/fume/gas/mist/vapors/spray   P301 + P330 + P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting   P310: Immediately call a POISON CENTER or doctor/physician
Hazard	F: Highly flammable   C: Corrosive
Risk	15: Contact with water liberates extremely flammable gases.   35: Causes severe burns.
Categories	^
	Preparation, Purification and Analysis  >  Stable Isotopes
Applications	^
	Function Transformation Type Caveat Reference     Reagent Asymmetric synthesis Reduction Mild, chemoselective reducing agent for the carbonyl function, but essentially inert to other functional groups e.g. epoxides, esters, lactones, carboxylic acid salts, nitriles and nitro groups. JOC 1987, 52, 5406   Reagent Organometallic Chemistry Hydrometallation Catalyzes [2+2] cycloadditions.     Reagent Reduction Aldehyde to alcohol In aprotic solvents such as dioxane. FF 1967, I, 584   Reagent Reduction Alkyl halide to alkane FeCl3 in ether converts epoxides to chlorohydrins. JOC 1982, 47, 276   Reagent Reduction Amide to aldehyde Deprotection of a silyl ether. TL 1981, 22, 3815   Reagent Reduction Amide to amine ?,?-Unsaturated ketones are reduced to allylic alcohols.     Reagent Reduction Anhydride to alcohol LaCl3 has been used for acetalization and thioacetalization of aldehydes and ketones.     Reagent Reduction Carboxylic acid to alcohol Amines can be formed from the reduction of azides and hydrazines.     Reagent Reduction Carboxylic ester to alcohol Reductive amination between a ketone and an amine gives a good yield of dialkylamine.     Reagent Reduction Epoxide to alcohol   COS 1991, 8, Chapters 1.1-4.8   Reagent Reduction Ketone to alcohol Oxazoles are reduced to amides and piderines are reduced to piperidines.     Reagent Reduction Nitrile to amine A dilute solution of CPA in isopropanol is used as the catalyst for Hydrosilylation of alkenes and alkynes to give alkylsilanes and alkenylsilanes. Hydrosilylation followed by hydrogen peroxide oxidation provides alcohols (from alkenes) and ketones (from     Reagent Reduction Nitro to amine Will do hetero-Diels-Alder reactions via intermediate diacylimines.     Reagent Reduction Tosylate to alkane Vinylic sulfones are reduced to the corresponding alkenes with retention of configuration. TL 1978, 1657
Other	^
Parameter	EINECS  237-980-6   Solubility  Solubility in water: Reacts Solubility in other solvents: Soluble in diethyl ether and THF Slightly soluble in other low molecular weight ethers   Origin  synthetic
3D model	Show